Atomically precise Au 24 (SR) 20 nanoclusters with multiemission
- Weijie Ji
- Guiying He
- Zhongyu Liu
- Yitong Wang
- Christopher G. Gianopoulos
- Amber Chang
- Lianshun Luo
- Avirup Sardar
- Sihan Chen
- Kristin Kirschbaum
- Xiaowei Wang
- Jiafeng Zhang
- Rongchao Jin
2026-08-05
Atomically precise metal nanoclusters (NCs) offer distinct platforms for exquisite control over photophysics, yet their complex photoluminescence (PL) mechanisms remain elusive. Here, we investigate a correlated series of Au 24 (SR) 20 with the same core but different R groups, revealing a unified triple-emission mechanism modulated by the R groups. By integrating cryogenic PL, femtosecond transient absorption and time-resolved electron paramagnetic resonance, we provide the first direct experimental “fingerprint” of short-lived excited triplet state (T 1 ) of ∼350-nanosecond lifetime at room temperature, resolving the exciton relaxation cascade from the initial singlet state (S 1 ) to a distorted singlet state with charge-transfer character to a T 1 . These states contribute to multiemission (600 to 1400 nanometers, visible to near-infrared). Crucially, the R group symmetry of the 3,5-dimethylbenzylthiolate ligand-induced locking increases the kinetic barrier for structural distortion. This rigidity inhibits S 1 rotational relaxation and decelerates intersystem crossing, yielding enhanced solution fluorescence. This study proposes a paradigm for designing efficient, multiemissive NCs by manipulating the excited-state dynamics and spin character.