Hexafluorophosphate additive enables durable seawater oxidation at ampere-level current density
- Xun He
- Yongchao Yao
- Limei Zhang
- Hefeng Wang
- Hong Tang
- Wenlong Jiang
- Yuchun Ren
- Jue Nan
- Yongsong Luo
- Tongwei Wu
- Fengming Luo
- Bo Tang
- Xuping Sun
2025-05-29
Direct seawater electrolysis at ampere-level current densities, powered by coastal/offshore renewables, is an attractive avenue for sustainable hydrogen production but is undermined by chloride-induced anode degradation. Here we demonstrate the use of hexafluorophosphate (PF₆⁻) as an electrolyte additive to overcome this limitation, achieving prolonged operation for over 5,000 hours at 1 A cm −2 and 2300 hours at 2 A cm −2 using NiFe layered double hydroxide (LDH) as anode. Together with the experimental findings, PF₆⁻ can intercalate into LDH interlayers and adsorb onto the electrode surface under an applied electric field, blocking Cl⁻ and stabilizing Fe to prevent segregation. The constant-potential molecular dynamics simulations further reveal the accumulation of high surface concentrations of PF 6 − on the electrode surface that can effectively exclude Cl − , mitigating corrosion. Our work showcases synchronous interlayer and surface engineering by single non-oxygen anion species to enable Cl − rejection and marks a crucial step forward in seawater electrolysis.