PNAS

Isobaric counterdiffusion of carbon tetrafluoride breathing gas to prevent severe decompression sickness

2026-08-10

Decompression sickness (DCS) risk limits human undersea operations through tissue inert gas supersaturation and pathological bubble formation. Switching the inert breathing gas prior to decompression to a gas with lower diffusivity could allow faster and safer decompression. This principle was tested in 20 kg swine after a helium-oxygen (He/O 2 ) dive using carbon tetrafluoride. Sedated swine breathed He/O 2 79/21 at a pressure equivalent of 200 feet of seawater (714 kPa) in a hyperbaric chamber for 50 min until randomized to continuing He/O 2 or switching to carbon tetrafluoride and oxygen (CF 4 /O 2 79/21) for 10 min before decompression. The CF 4 /O 2 group had reduced DCS with lower mortality, hypoxemia, pulmonary edema, venous gas emboli, gait disturbance, rash, and central nervous system hemorrhage. CF 4 /O 2 has the potential to expand human exploration through enabling deeper dives, longer dives, and rapid decompression while maintaining safety.

Full text

DOI https://doi.org/10.1073/pnas.2600125123